Melt inclusion analysis of the Unzen 1991–1995 dacite: implications for crystallization processes of dacite magma

Dacitic magma, a mixture of high-temperature (T) aphyric magma and low-T crystal-rich magma, was erupted during the 1991–1995 Mount Unzen eruptive cycle. Here, the crystallization processes of the low-T magma were examined on the basis of melt inclusion analysis and phase relationships. Variation in water content of the melt inclusions (5.1–7.2 wt% H₂O) reflected the degassing history of the low-T magma ascending from deeper levels (250 MPa) to a shallow magma chamber (140 MPa). The ascent rate of the low-T magma decreased markedly towards the emplacement level as crystal content increased. Cooling of magma as well as degassing-induced undercooling drove crystallization. With the decreasing ascent rate, degassing-induced undercooling decreased in importance, and cooling became more instrumental in crystallization, causing local and rapid crystallization along the margin of the magma body. Some crystals contain scores of melt inclusions, whereas there are some crystals without any inclusions. This heterogeneous distribution suggests the variation in the crystallization rate within the magma body; it also suggests that cooling was dominant cause for melt entrapment. Numerical calculations of the cooling magma body suggest that cooling caused rapid crystal growth and enhanced melt entrapment once the magma became a crystal-rich mush with evolved interstitial melt. The rhyolitic composition of melt inclusions is consistent with this model.Editorial responsibility: H Shinohara     

Phase Relations on the Actinolite-Pargasite Join

Phase relations along the join Ca₂Mg₄Fe²⁺Si₈O₂₂ (OH)₂ (Actinolite)-NaCa₂Mg_3?2Fe_0?8²⁺AlSi₆Al₂O₂₂(OH)₂ (Pargasite) have been studied at P_H2O = 1 kb andthe oxygen fugacities defined by the iron-wustite(IW) buffer. Actinolite and bornblende are separated by a solvus and thefield of actinolite+hornblende+vapor is present in the regionbetween Ac₈₅Pa₁₅ and Ac₅₅ Pa₄₅ at 680 ?C. Complete miscibilityis achieved at 720 ?C. At temperatures higher than the solvusthere is a continuous solid solution series between the twoend members. The stability field of amphibole solid solutiongradually increases with increasing pargasite content in actinolite.The phase assemblages at temperatures higher than those of asolid solution series between the two end members change withincreasing pargasite content in the bulk composition as follows;Act+Cpx+Qz+V, ActHbl+Cpx+Opx+Qz+V, Hbl+Cpx+Opx+Pl+V and Hbl+Cpx+Pl+Ol+V. In comparison with the Fe-free system, the extent of the miscibilitygap between actinolite and hornblende is reduced by an increasein the Fe²⁺ content. The present study should provide an adequatebasis for the interpretation of actinolite-hornblende pairsin metamorphic rocks.     

A trace-element geochemical model for imperfect fractional crystallization associated with the development of crystal zoning

Although many petrological studies of volcanic rocks have suggested that crystallization proceeds within magma bodies, highly compatible trace elements do not display the marked variations and extreme depletions predicted to result from perfect fractional crystallization. Imperfect crystal-liquid separation is a key process in explaining this paradox. The presence of suspended crystals greatly affects variations in highly compatible elements, and has been quantitatively modeled by assuming perfect equilibrium between the suspended crystals and the liquid (equilibrium crystallization and imperfect separation; ECIS); however, volcanic rocks generally contain zoned phenocrysts that reflect the absence of solid-state equilibration. The present study develops a mass-balance model for zoned crystallization and imperfect separation (ZCIS). The ZCIS process is more efficient than the conventional ECIS process in generating depleted compatible elements. These two end-member models are able to explain the compositional range of igneous rocks that experienced imperfect fractional crystallization under natural conditions. The predicted compositional regions in bivariate trace-element diagrams successfully account for the sizes and shapes of the regions defined by whole-rock and melt-inclusion data from the Bishop Tuff, CA, USA.     

Characterization of water quality variation in the Mekong River at Vientiane by frequent observations

To better understand the variation of water quality in the Mekong River, sampling and measurement were scheduled twice a week for about 3 years at Vientiane, followed by basic statistical analysis of the observed data. The frequent measurement revealed detailed characteristics of the water quality variation, which had not been detected by monthly observation in the previous studies. The variation in total ionic content was considered to be governed by dilution of the amount of water. Increases in turbidity could be attributed to physical effects including surface soil erosion and bed material resuspension at the time of discharge increase. Nitrogen concentrations were stably low during the low flow period and abruptly increased in May. After the annual maximum in late May, the nitrate concentration steadily decreased regardless of the remarkable rise in the discharge from mid‐July, whereas the ammonium concentration remained at a similar level until October. It was considered that the first small discernable runoff after the long dry season flushed the accumulated nitrogen in the surface soil and mobilized the nitrogen in the riverbed. The variation in phosphorus concentrations was different from that in nitrogen concentrations. During the high flow period, continual dilutions at discharge peaks and occasional large additions of phosphorus by surface runoff were suggested. Copyright © 2011 John Wiley & Sons, Ltd.     

The development of Fe-nodules surrounding biological material mediated by microorganisms

Takashikozo is a phenomenon of Quaternary sediments in Japan. They are cylindrical Fe-oxyhydroxide nodules that form as plaques round plant roots, where Fe is preferentially concentrated to develop a solid wall. Structural features suggest that after the roots have decayed, the central space where the roots were situated acts as a flow path for oxidized water. Analysis of microbial 16S rDNA extracted from the nodules identified iron-oxidizing bacteria encrusted round the roots where they are the likely initiators of nodule formation. Direct microscopic observation revealed an accumulation of Fe-oxyhydroxides that fill the pore spaces and is also likely to be linked with the encrusting microbial colonies. Geological history and nanofossil evidence suggest that these Fe-nodules may have been buried at a depth of up to several tens of meters for at least 10⁵ years in reducing Quaternary sediments. Thus Fe-oxyhydroxide nodules that have formed in a geological environment at the interfaces between water and rock by microbial mediation can persist under reducing conditions. If this is the case, the phenomenon is significant as an analogue of post-closure conditions in radioactive waste repositories, since it could influence nuclide migration.     

The Cretaceous Ofuku Pluton and Its Relation to Mineralization in the Western Akiyoshi Plateau,Yamaguchi Prefecture,Japan

The relationship between the magmatism of the Cretaceous Ofuku pluton and mineralization in and around the Akiyoshi Plateau, Yamaguchi Prefecture, Japan was investigated using a combination of field observation, petrographic and geochemical analyses, K–Ar geochronology, and fluid inclusion data. The Ofuku pluton has a surface area of 1.5 × 1.0 km, and was intruded into the Paleozoic accretionary complexes of the Akiyoshi Limestone, Ota Group and Tsunemori Formation in the western part of the Akiyoshi Plateau. The pluton belongs to the ilmenite‐series and is zoned, consisting mainly of early tonalite and granodiorite that share a gradational contact, and later granite and aplite that intruded the tonalite and granodiorite. Harker diagrams show that the Ofuku pluton has intermediate to silicic compositions ranging from 60.4 to 77.9 wt.% SiO₂, but a compositional gap exists between 70.5 to 73.4 wt.% SiO₂ (anhydrous basis). Modal and chemical variations indicate that the assumed parental magma is tonalitic. Quantitative models of fractional crystallization based on mass balance calculations and the Rayleigh fractionation model using major and trace element data for all crystalline phases indicate that magmatic fractionation was controlled mainly by crystal fractionation of plagioclase, hornblende, clinopyroxene and orthopyroxene at the early stage, and quartz, plagioclase, biotite, hornblende, apatite, ilmenite and zircon at the later stage. The residual melt extracted from the granodiorite mush was subsequently intruded into the northern and western parts of the Ofuku pluton as melt lens to form the granite and aplite. The age of the pluton was estimated at 99–97 Ma and 101–98 Ma based on K–Ar dating of hornblende and biotite, respectively. Both ages are consistent within analytical error, indicating that the Ofuku pluton and the associated Yamato mine belong to the Tungsten Province of the San‐yo Belt, which is genetically related to the ilmenite‐series granitoids of the Kanmon to Shunan stages. The aplite contains Cl‐rich apatite and REE‐rich monazite‐(Ce), allanite‐(Ce), xenotime and bastnäsite‐(Ce), indicating that the residual melt was rich in halogens and REEs. The tonalite–granodiorite of the Ofuku pluton contains many three‐phase fluid inclusions, along with daughter minerals such as NaCl and KCl, and vapor/liquid (V/L) volume ratios range from 0.2 to 0.9, suggesting that the fluid was boiling. In contrast, the granite and aplite contain low salinity two‐phase inclusions with low V/L ratios. The granodiorite occupies a large part of the pluton, and the inclusions with various V/L ratios with chloride daughter minerals suggest the boiling fluids might be related to the mineralization. This fluid could have carried base metals such as Cu and Zn, forming Cu ore deposits in and around the Ofuku pluton. The occurrence and composition of fluid inclusions in the igneous rocks from the Akiyoshi Plateau are directly linked to Cu mineralization in the area, demonstrating that fluid inclusions are useful indicators of mineralization.     

Paleostress orientation from 3-D orientation distribution of microcracks in quartz from the Cretaceous granodiorite core samples drilled through the Nojima Fault, south-west Japan

Abstract The orientations of both healed extension microcracks and microcracks in quartz grains sealed mostly by carbonate minerals were measured from Cretaceous granodiorite core samples drilled along the Nojima Fault, southwest Japan. The preferred orientations of both healed and sealed microcracks consist of approximately three orthogonal sets, (components) A, B and C, in which A strikes NS–NW-SE and dips vertically, B strikes EW–NE-SW and dips vertically, and C is subhorizontal. Both the healed and sealed microcracks were possibly formed by hydraulic fracturing, and the successive release of tensile stress due to pore fluid overpressure in the principal stress directions could have caused this microcracking in mutually orthogonal directions. The quartz grains are also very moderately plastically deformed, which is indicated by the occurrence of kink bands and undulose extinction. The association of healed microcracks and kink bands in the quartz suggests that these microstructures formed under subgreenschist facies conditions (≈300°C) during hydrothermal activity that could have occurred immediately after the emplacement of granodiorite during the Late Cretaceous period. Based on both the preferred orientation of microcracks, and c-axis fabrics of kinked and unkinked grains (so called kink method), it is inferred that the σ₁-and σ₃-axis were oriented horizontally in NS–NW-SE and EW–NE-SW directions, respectively. The inferred paleostress field does not conform to the east–west-trending compression during the Quaternary period, but to the activation of EW–NE-SW-trending, left–lateral strike–slip faults during the Late Cretaceous period in southwest Japan.     

Evidence from the Rb‐Sr system for 4.4 Ga alteration of chondrules in the Allende (CV3) parent body

Abstract— The timing and processes of alteration in the CV parent body are investigated by the analysis of Sr isotopes, major and trace elements, and petrographic type and distribution of the secondary minerals (nepheline and sodalite) in 22 chondrules from the Allende (CV3) chondrite. The Sr isotopic compositions of the chondrules are scattered around the 4.0 Ga reference line on the ⁸⁷Sr/⁸⁶Sr evolution diagram, indicating that the chondrules have been affected by late thermal alteration event(s) in the parent body. The degree of alteration, determined for individual chondrules based on the distribution of nepheline and sodalite, is unrelated to the disturbance of the Rb‐Sr system, suggesting that the alteration process that produced nepheline and sodalite is different from the thermal process that disturbed the Rb‐Sr system of the chondrules. Considering the geochemical behavior of Rb and Sr, the main host phase of Sr in chondrules is likely to be mesostasis, which could be most susceptible to late thermal alteration. As there is a poor connection between the alteration degree determined from abundances of nepheline and sodalite and the disturbance of Rb‐Sr isotopic system, we consider the mesostasis to provide a constraint on the late parent body alteration process. From this point of view, 23 mesostasis‐rich chondrules, including those from literature data, were selected. The selected chondrules are closely correlated on the ⁸⁷Sr/⁸⁶Sr evolution diagram, with an inferred age of 4.36 ± 0.08 Ga. This correlation would represent an age of the final major Sr isotopic redistribution of the chondrules in the parent body.     

Lithium and strontium isotopic systematics in playas in Nevada,USA: constraints on the origin of lithium

Lithium-rich brine in playas is a major raw material for lithium production. Recently, lithium isotopic ratios (δ⁷Li) have been identified as a tool for investigating water–rock interactions. Thus, to constrain the origin of lithium in playas by the use of its isotopes, we conducted leaching experiments on various lacustrine sediment and evaporite deposit samples collected from playas in Nevada, USA. We determined lithium and strontium isotopic ratios and contents and trace element contents of the leachate, estimated the initial δ⁷Li values in the water flowing into the playas, and examined the origin of lithium in playas by comparison with δ⁷Li values of the possible sources. In samples from the playas, δ⁷Li values show some variation, reflecting differences both in isotopic fractionation during mineral formation and in initial δ⁷Li value in water flowing into each playa. However, all δ⁷Li values in this study are much lower than those in river water and groundwater samples from around the world, but they are close to those of volcanic rocks. Considering the temperature dependence of lithium isotopic fractionation between solid and fluid, these results indicate that the lithium concentrated in playas in Nevada was supplied mainly through high-temperature water–rock interaction associated with local hydrothermal activity and not directly by low-temperature weathering of surface materials. This study, which is the first to report lithium isotopic compositions in playas, demonstrates that δ⁷Li may be a useful tracer for determining the origin of lithium and evaluating its accumulation processes in playas.     

U–Pb zircon age from the radiolarian‐bearing Hitoegane Formation in the Hida Gaien Belt,Japan

The dating of radiolarian biostratigraphic zones from the Silurian to Devonian is only partially understood. Dating the zircons in radiolarian‐bearing tuffaceous rocks has enabled us to ascribe practical ages to the radiolarian zones. To extend knowledge in this area, radiometric dating of magmatic zircons within the radiolarian‐bearing Hitoegane Formation, Japan, was undertaken. The Hitoegane Formation is mainly composed of alternating beds of tuffaceous sandstones, tuffaceous mudstones and felsic tuff. The felsic tuff and tuffaceous mudstone yield well‐preserved radiolarian fossils. Zircon grains showing a U–Pb laser ablation–inductively coupled plasma–mass spectrometry age of 426.6 ± 3.7 Ma were collected from four horizons of the Hitoegane Formation, which is the boundary between the Pseudospongoprunum tauversi to Futobari solidus–Zadrappolus tenuis radiolarian assemblage zones. This fact strongly suggests that the boundary of these assemblage zones is around the Ludlowian to Pridolian. The last occurrence of F. solidus is considered to be Pragian based on the reinterpretation of a U–Pb sensitive high mass‐resolution ion microprobe (SHRIMP) zircon age of 408.9 ± 7.6 Ma for a felsic tuff of the Kurosegawa belt, Southwest Japan. Thus the F. solidus–Z. tenuis assemblage can be assigned to the Ludlowian or Pridolian to Pragian. The present data also contribute to establishing overall stratigraphy of the Paleozoic rocks of the Fukuji–Hitoegane area. According to the Ordovician to Carboniferous stratigraphy in this area, Ordovician to Silurian volcanism was gradually reduced to change the sedimentary environment into a tropical lagoon in the early Devonian. And the quiet Carboniferous environment was subsequently interrupted, throwing it once more into the volcanic conditions in the Middle Permian.